Green synthesis approach for preparing zeolite based Co-Cu bimetallic catalysts for low temperature CO2 hydrogenation to methanol
نویسندگان
چکیده
• Green synthesis of zeolite based Cu-Co bimetallic catalysts for methanol production in slurry reactor. synergism over CO 2 hydrogenation to has not yet been reported the literature. Structure-activity relationship methanol. In this study, were synthesized by green deposition precipitation method. To investigate optimum metal-metal ratio, with different metal weight ratios evaluated The XRD analysis revealed crystalline nature support highly dispersed oxides. FESEM observation showed well morphology catalysts. nitrogen adsorption-desorption studies that surface area was slightly decreased increasing Cu content Temperature program reduction exhibited between metals which resulted variation behavior Similarly, XPS interaction shifting peaks higher binding energies regions. desorption investigations existence three types basic sites on Activity profiles examined low temperature activity documented enhancement rate from 7.5 25.6 g/Kg cat .h Based physico-chemicals findings and data, structure-activity patterns elaborated details.
منابع مشابه
Low temperature methanol synthesis from CO hydrogenation over Cu-based catalyst
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متن کاملResponse to Comment on "Active sites for CO2 hydrogenation to methanol on Cu/ZnO catalysts".
In their Comment on the our recent Report, Nakamura et al argue that our x-ray photoelectron spectroscopy (XPS) analysis was affected by the presence of formate species on the catalyst surface. This argument is not valid because the reactant gases were evacuated at temperatures from 525 to 575 kelvin, conditions under which formate is not stable on the catalyst surface. An analysis of the XPS r...
متن کاملComment on "Active sites for CO2 hydrogenation to methanol on Cu/ZnO catalysts".
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ژورنال
عنوان ژورنال: Fuel
سال: 2022
ISSN: ['0016-2361', '1873-7153']
DOI: https://doi.org/10.1016/j.fuel.2022.125643